Reactions of Chlorine Dioxide with Unsaturated Compounds. II. Methyl Oleate.
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منابع مشابه
Reactions of aqueous chlorine and chlorine dioxide with model food compounds.
Chlorine and chlorine dioxide (ClO2), common disinfecting and bleaching chemicals used in the food industry, are potent oxidizing and chlorinating agents. Unfortunately, little is known about the nature of the reactions of chlorine with organic food constituents. This presentation reviews published information concerning the reactions of chlorine gas (Cl2[g]), aqueous chlorine, and ClO2 with mo...
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cis-[Ru(2,9-Me(2)phen)(2)(OH(2))(2)](2+) reacts readily with chlorite at room temperature at pH 4.9 and 6.8. The ruthenium(II) complex can catalyze the disproportionation of chlorite to chlorate and chloride, the oxidation of chlorite to chlorine dioxide, as well as the oxidation of alcohols by chlorite.
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N-Methyl-N-((trimethylsilyl)methyl)aniline was employed as reagent in visible-light-induced, iridium-catalyzed addition reactions to cyclic α,β-unsaturated carbonyl compounds. Typical reaction conditions included the use of one equivalent of the reaction substrate, 1.5 equivalents of the aniline and 2.5 mol % (in MeOH) or 1.0 mol % (in CH2Cl2) [Ir(ppy)2(dtbbpy)]BF4 as the catalyst. Two major re...
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Chlorine dioxide (ClO2) is an antimicrobial recognized for its disinfectant properties since the early 1900's (EPA, 2005). This compound effectively kills microorganisms including bacteria, viruses or fungi on inanimate objects, foods, and other surfaces (EPA, 2005). Chlorine dioxide can be generated in a gas or liquid form and smells like chlorine bleach (EPA, 2005). In 1967, the Environmental...
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The kinetics of phenol oxidation with chlorine dioxide in different solvents (2 methylpropan 1 ol, ethanol, 1,4 dioxane, acetone, acetonitrile, ethyl acetate, dichloromethane, heptane, tetrachloromethane, water) was studied by spectrophotometry. In all solvents indicated, the reaction rate is described by an equation of the second order w = k[PhОН]•[ClO2]. The rate constants were measured (at 1...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1966
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.20-0211